Interaction between fixed geometry α, β-unsaturated ketones with phenylhydrazine

  • Sigita Višniakova
  • Albinas Žilinskas
  • Jurgis Sūdžius
  • Linas Labanauskas
Keywords: bicyclo[3.3.1]nonane, Claisen-Schmidt reaction, pyrazole

Abstract

The condensation reaction between benzaldehyde and bicyclo[3.3.1]nonanones in the presence of solid NaOH performed upon grinding without any solvent resulted in the corresponding α, β-unsaturated derivatives. These compounds were used as precursors for fused pyrazole and bicyclo[3.3.1]nonane derivatives.

Published
2014-04-07
Section
Organic Chemistry